波谱学杂志

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一种新型香豆素[3,4]吡啶酮衍生物的合成与结构确证

赵盼, 王焮垭, 高贺闻, 秘云哲, 王韦丰, 袁金伟   

  1. 河南工业大学化学化工学院,河南 郑州 450001
  • 收稿日期:2026-03-17 修回日期:2026-04-19 接受日期:2026-05-11
  • 通讯作者: 袁金伟 E-mail:yuanjinweigs@126.com
  • 基金资助:
    河南省自然科学基金项目(262300421674)

Synthesis and Structural Elucidation of Coumarin-3,4-pyridone Derivative

ZHAO Pan,WANG Xinya,GAO Hewen,BI Yunzhe,WANG Weifeng, YUAN Jinwei   

  1. School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, China
  • Received:2026-03-17 Revised:2026-04-19 Accepted:2026-05-11
  • Contact: YUAN Jinwei E-mail:yuanjinweigs@126.com
  • Supported by:
    Natural Science Foundation of Henan Province(262300421674)

摘要: 香豆素[3,4]吡啶酮衍生物是一类以香豆素为母体的新型芳香杂环化合物.本文为香豆素[3,4]吡啶酮衍生物的合成提供了一种新的合成方法,并对其红外吸收光谱(IR)、质谱(MS)及核磁共振(NMR)波谱(包括1H NMR、13C NMR、DEPT135、COSY、HSQC、HMBC)进行了测定,分析了其IR谱图特征吸收峰对应的基团,对其1H和13C NMR信号进行了归属,确证了香豆素[3,4]吡啶酮衍生物的结构.该研究将为香豆素[3,4]吡啶酮衍生物的其他相关研究提供参考.

关键词: 核磁共振(NMR), 香豆素[3,4]吡啶酮衍生物, 结构确证, 红外光谱(IR), 质谱(MS)

Abstract:

Coumarin-3,4-pyridone derivatives are a novel class of aromatic heterocyclic compounds based on the coumarin scaffold. This work presents a new synthetic method for the preparation of coumarin-3,4-pyridone derivatives. The infrared absorption spectrum, mass spectrum (MS), and nuclear magnetic resonance (NMR) spectra, including 1H NMR, 13C NMR, DEPT135, COSY, HSQC and HMBC, were measured and analyzed. The characteristic absorption peaks in the IR spectra were assigned to their corresponding functional groups, and the signals in the 1H and 13C NMR spectra were interpreted and assigned, thereby confirming the structure of the coumarin-3,4-pyridone derivatives. This study provides a reference for further research on coumarin-3,4-pyridone derivatives.

Key words: Nuclear magnetic resonance (NMR), coumarin-3,4-pyridone derivative, structural eleucidation, infrared spectrum (IR), mass spectrometry (MS)