对雷酚内酯对照品的紫外吸收光谱（UV）、红外吸收光谱（IR）、质谱（MS）、核磁共振（NMR）谱（包括1H NMR、13C NMR、DEPT、1H-1H COSY、NOE、1H-13C HSQC和1H-13C HMBC谱图）进行了分析，对其1H和13C NMR谱峰进行了全归属，纠正了文献[5]的归属错误，确证了雷酚内酯对照品的化学结构.
戴忠
,
张聿梅
,
何轶
,
马双成
,
王菲菲
,
刘斌
. 雷酚内酯的波谱学数据与结构确证[J]. 波谱学杂志, 2017
, 34(1)
: 35
-42
.
DOI: 10.11938/cjmr20170105
Ultraviolet (UV) spectrum, infrared (IR) spectrum, mass (MS) spectra and nuclear magnetic resonance (NMR) spectra (i.e., 1H NMR, 13C NMR, DEPT, 1H-1H COSY, NOE, 1H-13C HSQC and 1H-13C HMBC) of Triptophnolide were collected and interpreted. All 1H and 13C NMR signals were assigned. Base on the data, the structure of reference standard Triptophnolide was determined.
[1] DENG F X, ZHOU B N, SONG G Q, et al. Research fromTripterygium Wilfordii Hook. F.[J]. Acta Pharmaceutica Sinica, 1982, 17(2):146-150. 邓福孝, 周炳南, 宋国强, 等. 雷公藤化学成分的研究Ⅲ. 两种新二萜内酯——雷酚内酯甲醚和雷酚新内酯的分离及结构[J]. 药学学报, 1982, 17(2):146-150.
[2] XU B, DU J O. Study on polarographic catalytic wave of triptophenolide[J]. Chinese Journal of Analysis Laboratory, 2005, 24(4):49-52. 徐斌, 杜俊鸥. 雷酚内酯的极谱催化波研究[J]. 分析试验室, 2005, 24(4):49-52.
[3] FAN X W, LIU L H, WEI W X, et al. One stereoisomer of triptophenolide isolated from Tripterygium Wilfordii Hook. F. by high-speed countercurrent chromatography[J]. Natural Product Research and Development, 2011, 23(6):1049-1051. 樊希望, 刘力恒, 韦万兴, 等. 高速逆流色谱分离雷公藤中的雷酚内酯异构体[J]. 天然产物研究与开发, 2011, 23(6):1049-1051.
[4] YU D F, HU B H, CHEN G P, et al. Structure cture revision of Triptophenolide[J]. Acta Pharmaceutica Sinica, 1990, 25(12):929-931. 于东防, 胡邦豪, 陈国平, 等. 雷酚内酯的结构修正[J]. 药学学报, 1990, 25(12):929-931.
[5] LIU Z Z, ZHAO R H, ZOU Z M. Chemical constituent root bark of Tripterygium hypoglaucum[J]. China J Chinese Materia Modica, 2011, 36(18):2503-2506. 刘珍珍, 赵荣华, 邹忠梅. 昆明山海棠根皮化学成分的研究[J]. 中国中药杂志, 2011, 36(18):2503-2506.
[6] XUE J, JIA X B, CHEN Y, et al. Chemical constituents of Tripterygium wilfordii Hook.f and its toxicity[J]. China J Traditional Chinese Medicine and Pharmacy, 2010, 25(5):726-733. 薛璟, 贾晓斌, 陈彦, 等. 雷公藤化学成分及其毒性研究进展[J]. 中华中医药杂志, 2010, 25(5):726-733.
