研究简报

季戊四醇硬脂酸酯同系物的结构解析

  • 李春发 ,
  • 刘广 ,
  • 王芹 ,
  • 刘征
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  • 沙伯基础(中国)研发有限公司, 上海 201319

收稿日期: 2017-12-18

  网络出版日期: 2018-08-28

Analyzing Pentaerythritol Stearate Homologs with NMR Spectroscopy

  • LI Chun-fa ,
  • LIU Guang ,
  • WANG Qin ,
  • LIU Zheng
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  • SABIC R & D Center(China) Co., Ltd., Shanghai 201319, China

Received date: 2017-12-18

  Online published: 2018-08-28

摘要

通过多种核磁共振(NMR)技术(包括1H NMR、定量13C NMR、DEPT135、1H-1H COSY、1H-1H NOESY、1H-13C HSQC和1H-13C HMBC)技术,对季戊四醇硬脂酸酯润滑剂的组成进行了表征.结果表明:该润滑剂主要成分是单季戊四醇四硬脂酸酯,同时还含有少量的单季戊四醇三硬脂酸酯、单季戊四醇双硬脂酸酯、双季戊四醇硬脂酸酯和三季戊四醇硬脂酸酯,以及微量的多季戊四醇硬脂酸酯.

本文引用格式

李春发 , 刘广 , 王芹 , 刘征 . 季戊四醇硬脂酸酯同系物的结构解析[J]. 波谱学杂志, 2018 , 35(3) : 363 -373 . DOI: 10.11938/cjmr20172612

Abstract

A pentaerythritol stearate sample with unknown composition was analyzed by nuclear magnetic resonance (NMR) spectroscopy (i.e., 1H NMR, quantitative 13C NMR, DEPT135, 1H-1H COSY, 1H-1H NOESY, 1H-13C HSQC and 1H-13C HMBC). The results indicated that the sample contained mainly monopentaerythritol tetrastearate, but also had small amounts of monopentaerythritol tristearate, monopentaerythritol distearate, dipentaerythritol stearate and tripentaerythritol stearate, as well as a trace amount of multipentaerythritol stearate.

参考文献

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