固体核磁共振技术在锂/钠离子电池碳负极中的应用及研究进展

雷振宇; 梁欣苗; 雷友义; 杨丽; 冯继文

doi:10.11938/cjmr20192732

波谱学杂志 >

2020 , Vol. 37 >Issue 1: 28 - 39

DOI: https://doi.org/10.11938/cjmr20192732

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固体核磁共振技术在锂/钠离子电池碳负极中的应用及研究进展

雷振宇 ,
梁欣苗 ,
雷友义 ,
杨丽 ,
冯继文

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1. 波谱与原子分子物理国家重点实验室, 武汉磁共振中心(中国科学院武汉物理与数学研究所), 湖北武汉 430071;
2. 中国科学院大学, 北京 100049

收稿日期: 2019-04-08

网络出版日期: 2019-05-05

基金资助

国家自然科学基金资助项目（11474314，21603267）.

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Progresses in Solid-State NMR Studies on Carbon Anode Materials for Lithium/Sodium-Ion Batteries

LEI Zhen-yu ,
LIANG Xin-miao ,
LEI You-yi ,
YANG Li ,
FENG Ji-wen

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1. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, National Center for Magnetic Resonance in Wuhan(Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences), Wuhan 430071, China;
2. University of Chinese Academy of Science, Beijing 100049, China

Received date: 2019-04-08

Online published: 2019-05-05

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摘要

碳负极材料作为锂/钠离子电池的传统负极材料一直获得广泛的推广和应用，但其仍存在充电时间长、库伦效率低等问题，研究碳负极材料充放电机理是解决这些问题的关键.固体核磁共振（NMR）技术是一种研究固体材料中目标原子所处化学环境以及材料内部结构变化的有效手段.通过测定锂/钠离子电池中⁶Li、⁷Li和²³Na高速魔角旋转（MAS）条件下的固体NMR谱图，能够清晰获得锂/钠离子电池碳负极脱/嵌过程中的结构变化，以及碳原子与Li/Na的配位情况，从而为碳负极材料的设计及其电化学性能的提升提供充分的理论依据.本文综述了近年来固体NMR技术在锂/钠离子电池碳负极材料研究中的应用以及相关研究进展.

关键词： 锂离子电池; 钠离子电池; 碳负极材料; 固体核磁共振

本文引用格式

雷振宇 , 梁欣苗 , 雷友义 , 杨丽 , 冯继文 . 固体核磁共振技术在锂/钠离子电池碳负极中的应用及研究进展[J]. 波谱学杂志, 2020 , 37(1) : 28 -39 . DOI: 10.11938/cjmr20192732

Abstract

Carbon anode material is a traditional and widely-used anode material for lithium/sodium-ion batteries. However, it still has some drawbacks, such as long charging time and low columbic efficiency. Studying the charging and discharging mechanisms of the carbon anode material will help to solve these problems. Solid-state nuclear magnetic resonance (NMR) is an effective method to study the chemical environment of target atoms in solid materials and structural changes of materials. By measuring high speed magic-angle spinning (MAS) spectrum of ⁶Li, ⁷Li and ²³Na in lithium/sodium-ion batteries, the structural changes during the process of de-intercalation and coordination between the carbon atoms and Li/Na atoms can be elucidated. The information obtained can provide a sufficient theoretical basis for designing of novel carbon anode materials and improving their electrochemical properties. This paper reviews the application and progresses of solid-state NMR technology in the research of carbon anode materials for lithium/sodium-ion battery.

Key words： lithium-ion batteries; sodium-ion batteries; carbon anode materials; solid-state nuclear magnetic resonance

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