波谱学杂志 >

2021 , Vol. 38 >Issue 4: 533 - 542

DOI: https://doi.org/10.11938/cjmr20212936

 

氧化物纳米材料表面结构与性质的固体核磁共振波谱研究

  • 夏锡锋 ,
  • 张文静 ,
  • 林芝晔 ,
  • 柯晓康 ,
  • 温玉洁 ,
  • 王芳 ,
  • 陈俊超 ,
  • 彭路明
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  • 1. 分析测试中心, 南京理工大学, 江苏 南京 210094
    2. 介观化学教育部重点实验室和生命化学协同创新中心, 化学化工学院, 南京大学, 江苏 南京 210023

收稿日期: 2021-07-13

  网络出版日期: 2021-08-18

基金资助

国家自然科学基金资助项目(91745202);国家自然科学基金资助项目(21972066);国家自然科学基金资助项目(21661130149)

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Solid-State NMR Studies on the Surface Structure and Properties of Oxide Nanomaterials

  • Xi-feng XIA ,
  • Wen-jing ZHANG ,
  • Zhi-ye LIN ,
  • Xiao-kang KE ,
  • Yu-jie WEN ,
  • Fang WANG ,
  • Jun-chao CHEN ,
  • Lu-ming PENG
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  • 1. Analysis and Testing Center, Nanjing University of Science and Technology, Nanjing 210094, China
    2. Key Laboratory of Mesoscopic Chemistry of Ministry of Education and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Received date: 2021-07-13

  Online published: 2021-08-18

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摘要

氧化物纳米材料的多种应用与其表面结构和性质密切相关.近年来，固体核磁共振波谱在相关研究中提供了关键信息.本综述总结了近期发展的、以固体核磁共振波谱为主的两种表征氧化物纳米材料表面结构和性质的方法，包括表面选择的同位素标记17O核磁共振波谱与动态核极化表面增强核磁共振波谱，并对氧化物纳米材料的固体核磁共振波谱研究的发展趋势进行了展望.

关键词： 氧化物纳米材料; 表面结构与性质; 氧-17; 固体核磁共振波谱; 动态核极化

本文引用格式

夏锡锋 , 张文静 , 林芝晔 , 柯晓康 , 温玉洁 , 王芳 , 陈俊超 , 彭路明 . 氧化物纳米材料表面结构与性质的固体核磁共振波谱研究[J]. 波谱学杂志, 2021 , 38(4) : 533 -542 . DOI: 10.11938/cjmr20212936

Abstract

Many applications of oxide nanomaterials depend on their surface structure and properties. Solid-state nuclear magnetic resonance (NMR) spectroscopy has been used to obtain such key information in related studies. This paper summarizes two recently developed approaches based on solid-state NMR spectroscopy for determining the surface structure and properties of oxide nanomaterials, including surface-selective isotopic labeling 17O NMR and dynamic nuclear polarization surface enhanced NMR spectroscopy. The development trend for investigating oxide nanomaterials with solid-state NMR spectroscopy is also introduced.

Key words： oxide nanomaterials; surface structure and properties; 17O; solid-state nuclear magnetic resonance spectroscopy; dynamic nuclear polarization

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