二氧化硅颗粒堆积空隙中氢气分子的核磁共振谱学特征研究
收稿日期: 2024-03-25
网络出版日期: 2024-05-06
基金资助
上海市科委“科技创新行动计划”项目(22142200800)
Studies on the 1H NMR Spectral Features of Hydrogen Molecules in the Interstices of SiO2 Particles
Received date: 2024-03-25
Online published: 2024-05-06
王行乐 , 邵正泽 , 董洪春 , 魏达秀 , 陈群 , 姚叶锋 . 二氧化硅颗粒堆积空隙中氢气分子的核磁共振谱学特征研究[J]. 波谱学杂志, 2024 , 41(3) : 315 -321 . DOI: 10.11938/cjmr20243104
1H NMR spectral features of hydrogen molecules in the stacking interstices of silicon dioxide (SiO2) microspheres with different sizes are studied in the present article. The chemical shift of hydrogen molecules is observed to gradually shift towards higher fields as the size of the stacking interstices decreases. Combined with experimental results of variable temperature hydrogen spectroscopy, self-diffusion coefficients measurement, and scanning electron microscopy, the observed phenomenon is attributed to two factors, namely, 1) the microsphere size-dependent local magnetic field inhomogeneity in the stacking interstices caused by the diamagnetic SiO2 microspheres; and 2) the rapid exchange among hydrogen molecules experiencing different local fields within the microsphere interstices. The results of this study demonstrate the potential of hydrogen gas as a probe molecule for measuring micro- and nano-scale pore sizes.
Key words： hydrogen gas; silicon dioxide; stacking interstices; NMR; chemical shift
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