Chinese Journal of Magnetic Resonance ›› 1996, Vol. 13 ›› Issue (5): 503-508.
Previous Articles
Xia Chungu, Li Dagang
Received:
Revised:
Published:
Online:
Abstract: An apparatus for the in situ NMR studies of intermediates on the homogeneous catalysis and synthesis of organophosphines is described. Using this technique, the hydroformylation of 1-hexene with rhodiumphosphine complex Rh(acac) (CO) (PPh3)under the industrial reaction conditions (H2/CO=1:1,1.5 MPa; 75~80℃) was studied.At same time, under the following reaction conditions:temperature 70~75℃, pressure 2.0MPa, solvent C6D6 and initiator AIBN, the reactions of PH3 with olefins containing N atoms were also studied.
Key words: In situ NMR
Xia Chungu, Li Dagang. IN SITU NMR TECHNIQUE AND APPLICATIONS[J]. Chinese Journal of Magnetic Resonance, 1996, 13(5): 503-508.
0 / / Recommend
Add to citation manager EndNote|Reference Manager|ProCite|BibTeX|RefWorks
URL: http://magres.apm.ac.cn/EN/
http://magres.apm.ac.cn/EN/Y1996/V13/I5/503
