ESR STUDY ON VO2+ PROBED ZEOLITE CARRIERS OF CATALYSTS FOR COPOLYMERIZATION

Chinese Journal of Magnetic Resonance ›› 1993, Vol. 10 ›› Issue (1): 25-30.

Previous Articles Next Articles

ESR STUDY ON VO²⁺ PROBED ZEOLITE CARRIERS OF CATALYSTS FOR COPOLYMERIZATION

Wang Li, Feng Linxian, Yang Shilin

Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027

Received:1992-01-25 Revised:1992-09-18 Published:1993-03-05 Online:2018-01-20
Supported by:
Program supported by National Natural Science Foundation of China

Abstract

Abstract: Using VO²⁺ as spin probe, the micro-environment of VO²⁺ supported on zeolite was observed by ESR technique. Computer program was built for simulating ESR spectra with complicated and multi-centers. It was found that the dispersion character of VO²⁺ is dependent upon the preparation conditions employed and the carriers chosen. This may serve as a new method to get micro-environment information of carriers and can be used in the choice of carriers of coordination catalysts.

Key words: ESR, Coordination copolymerization catalyst, Zeolite

Wang Li, Feng Linxian, Yang Shilin. ESR STUDY ON VO²⁺ PROBED ZEOLITE CARRIERS OF CATALYSTS FOR COPOLYMERIZATION[J]. Chinese Journal of Magnetic Resonance, 1993, 10(1): 25-30.

[1]	Rui QIN,Chao WANG,Qiang WANG,Min HU,Jin-lin LI,Jun XU,Feng DENG. Formation and Reactivity of Surface Methoxy Species in Methanol Conversion over SSZ-13 Zeolite [J]. Chinese Journal of Magnetic Resonance, 2022, 39(4): 439-447.
[2]	Shu ZENG, Shu-tao XU, Ying-xu WEI, Zhong-min LIU. Investigation of the Ethanol Dehydration to Ethene Reaction on H-SSZ-13 Molecular Sieve by in situ Solid-state NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2022, 39(2): 123-132.
[3]	Han-di CHEN,Hai-yu KONG,Zhen-chao ZHAO,Wei-ping ZHANG. Exploring the Na⁺ Locations and Al Distributions in SSZ-39 Zeolite by Solid-State NMR Spectroscopy and DFT Calculations [J]. Chinese Journal of Magnetic Resonance, 2021, 38(4): 543-551.
[4]	Yao XIAO,Chang-jiu XIA,Xian-feng YI,Feng-qing LIU,Shang-bin LIU,An-min ZHENG. Progress in the Studies on Sn-Zeolites by Solid-State Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2021, 38(4): 571-584.
[5]	GAO Xiu-zhi, ZHANG Yi, WANG Xiu-mei, ZHANG Zhi-hua, XU Guang-tong. Structure and Acidity Changes in Ultra-Stable Y Zeolites During Hydrothermal Aging: A Solid-State NMR Spectroscopy Study [J]. Chinese Journal of Magnetic Resonance, 2020, 37(1): 95-103.
[6]	YANG Xian-peng, YU Hao-jie, WANG Li. Recent Progresses in ESR Studies on Ferrocenyl Compounds [J]. Chinese Journal of Magnetic Resonance, 2016, 33(3): 491-501.
[7]	Yury V. BOGACHEV, Mikhail N. KNYAZEV, Yaroslav Yu. MARCHENKO. Compact ESR Equipment [J]. Chinese Journal of Magnetic Resonance, 2016, 33(1): 27-36.
[8]	LI Bo-jie，XU Jun，WANG Qiang，WANG Xiu-mei，QI Guo-dong，DENG Feng. Carbonylation of Methanol on Cu-H-MOR Zeolites: Insights from Solid-State NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2014, 31(3): 331-340.
[9]	JIANG Xiao-Ming, Ding-Ning, Zhao-Sui. An ESR Study on Sodium Alkylbenzensulfonate Micelles [J]. Chinese Journal of Magnetic Resonance, 2012, 29(3): 388-392.
[10]	LIU Wei-Hua, WANG Mou-Hua, WU Guo-Zhong. Radiation- and Thermal Treatment-Induced Radicals in Polyacrylonitrile Fibers Studied by ESR [J]. Chinese Journal of Magnetic Resonance, 2011, 28(4): 447-453.
[11]	SHEN Guang-Lai, SU Ji-Hu, CHEN Jia-Fu. Radiation Effect on Polytetrafluoroethylene Studied by ESR [J]. Chinese Journal of Magnetic Resonance, 2011, 28(4): 512-522.
[12]	JI Xue-Han, XU Xin-Sheng, CUI Zhi-Feng. Investigating Laser Photolyzed Radicals Using TR-ESR [J]. Chinese Journal of Magnetic Resonance, 2011, 28(4): 540-550.
[13]	ZHENG Rong-Ping, PAN Tie-Ying, SHI Xin-Mei, ZHOU Li-Fang, LIU Rui-Min, ZHANG De-Xiang, GAO Jin-Sheng . Quantitative Determination of Free Radical Content in Coal by Standard Curve Method [J]. Chinese Journal of Magnetic Resonance, 2011, 28(2): 259-264.
[14]	ZHAO Bao-Lu. Developments and Applications of ESR Spin Trapping Technique in the Biological and Medical Studies [J]. Chinese Journal of Magnetic Resonance, 2011, 28(1): 18-41.
[15]	Yei-Chen LAI , Yun-Wei CHIANG. Asymmetric Partition of Spin Labeled Lipids in the Coexistence of DPPC-Rich Ordered and DLPC-Rich Fluid Phases [J]. Chinese Journal of Magnetic Resonance, 2010, 27(3): 470-484.

ESR STUDY ON VO²⁺ PROBED ZEOLITE CARRIERS OF CATALYSTS FOR COPOLYMERIZATION

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments