Chinese Journal of Magnetic Resonance ›› 1988, Vol. 5 ›› Issue (2): 179-184.

Previous Articles     Next Articles

THE KINETIC STUDY OF THE ELIMINATION REACTION OF THE REACTIVE DYES CONTAINING α,β-DIBROMOPROPANAMIDE GROUP BY 1H-NMR METHOD

Tian Yazhen, Zhang Mingjia, Yan Guo, Li Jianfeng, Wu Zuwang   

  1. College of Chemical Engineering, Dalian Institute of Technology, Dalian
  • Received:1987-05-25 Revised:1987-07-17 Published:1988-06-05 Online:2018-01-22

Abstract: A kinetic study of the elimination of hydrogen bromide from α,β-dibromo-propanamide reactive dyes was made. Through 1H nuclear magnetic resonance tracing technique this elimination reaction was found to be a pseudofirst order reaction. The reaction rate constants in deuterium oxide at pH 7-9 and temperature 25-50℃ were determined.

Key words: 1H-NMR Spectrometry, Elimination reaction, α,β-Dibromopropa-namide dyes, α-Bromoacrylamide dyes, Reaction kinetics, Nuclear magnetic resonance tracing technique, Pseudofirst order reaction, Apparent rate constant