Chinese Journal of Magnetic Resonance ›› 1984, Vol. 1 ›› Issue (4): 353-360.

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29Si AND 13C NMR STUDIES OF CYCLODISILAZANE DERIVATIVES

Li Ercheng1, Xie Zemin1, Wang Jinting1, Xu Guangzhi1, C. H. Ye2   

  1. 1. Institute of Chemistry, Academia Sinica, Beijing;
    2. Institute of physics, Academia Sinica, Wuhan
  • Received:1984-04-23 Published:1984-06-05 Online:2018-01-23

Abstract: The 29Si and 13C NMR spectra of ten cyclodisilazane derivatives(R1=Me,ф;R2=Me,ф;R3=Me;X=Me,ф,OH、OSiMe3、Hand Cl) and nine related polymrfes(m=2,3,4,7 and 10)have been studied systematically. The effects of substituents X, R1 R2 and si-loxane chain length on chemcal shifts have also been discussed. The results show that there are (p-d)π interactions between N atom and three adjacent Si atoms in cyclodisilazanes.