Chinese Journal of Magnetic Resonance

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STRUCTURAL DETERMINATION OF PETROVIIN FROM SAUSSUREA PETROVII BY 2D NMR

DAI Jing-qiu, LIU Zhong-li, YANG Li*   

  1. National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 7 30000, China
  • Received:2001-11-19 Revised:2001-12-28 Published:2002-06-05 Online:2002-06-05
  • About author:*Correspondence author
  • Supported by:

    “973”项目(G1998051113).

Abstract:

From the Inner Mongolia medicinal plant, Saussurea petrovii, which was coll ecte d in the suburb of Lanzhou city, Gansu province of China, a colourless gum compo und was isolated. The compound was identified as a new eudesmane type sesquiterp ene ester, petroviin, by MS and NMR. The structure of petroviin was determined b y two-dimensional NMR spectroscopy for the first time. All the 1H and 13C NMR resonances   were assigned unambiguously. The relative configuration of petroviin was also  evaluated.

Key words: saussurea petrovii, eudesmane, 2D NMR

CLC Number: