Chinese Journal of Magnetic Resonance

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FOUR CAFFEOYLQUINIC ACIDS FROM MORINA NEPALENSIS VAR. ALBA HAND.-MAZZ.

TENG Rong-wei1, ZHOU Zhi-hong2,  WANG De-zu1, YANG Chon g-ren1*   

  1. 1.Kunming Institute of Botany,  Chinese Academy of Sciences, Kuming 650204, China;
    2.Kungming Institute of Medicine of Biologic Valley, Kunming 650108, China
  • Received:2001-08-13 Revised:2001-11-05 Published:2002-06-05 Online:2002-06-05
  • About author:*Correspondence author: E-mail:cryang@public.km.yu.cn.

Abstract:

Four compounds were isolated from water-soluble part of whole plant of Morina nepalensis var. alba Hand.-Mazz.by CC on Si gel, RP-8, Sephadex LH-20. Based on spectroscopic evidences,  their structures were elucidated as 3-O-caffeoyl-quinic acid (1), 3, 5-O-dicaffeoyl-quinic acid (2), 3,  4-O- dicaffeoyl-quinic acid (3] ) and 4, 5-O- dicaffeoyl-quinic acid (4), respectively. Complet e assignments of 1H and 13C spectra of these four compounds were obtained by 2D NMR spe ctra. Furtherm ore, 1H and 13C Chemical shifts of compound 1 and 2 were determined with both in CD3OD and DMSO-d6 solvent. All four compounds were firstly isolated from the Morin a plants. 

Key words: morina nepalensis var. alba Hand.-Mazz, dipsacaceae, morina, caffeo ylquinic acids, NMR complete assignments

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