Chinese Journal of Magnetic Resonance >

2020 , Vol. 37 >Issue 1: 1 - 15

DOI: https://doi.org/10.11938/cjmr20192779

Review Articles

Quantitative Cross Polarization Magic-Angle Spinning NMR Spectroscopy in Solids

  • LIANG Li-xin ,
  • DENG Feng ,
  • HOU Guang-jin
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  • 1. State Key Laboratory of Catalysis, National Laboratory for Clean Energy, Collaborative Innovation Center of Chemistry for Energy Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
    2. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, National Center for Magnetic Resonance in Wuhan(Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences), Wuhan 430071, China;
    3. University of Chinese Academy of Sciences, Beijing 100049, China

Received date: 2019-08-29

  Online published: 2019-10-16

Supported by

the National Natural Science Foundation of China (21773230); Liaoning Revitalization Talents Program (XLYC1807207); Innovation Foundation of Dalian Institute of Chemical Physics (Y7611105T5).

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Abstract

The combination of cross polarization and magic-angle spinning (CP/MAS), is a routine technique for signal enhancement in solid-state nuclear magnetic resonance (NMR) spectrum. With CP/MAS, the acquisition efficiency of solid-state NMR experiments can be improved greatly. However, the enhanced signal is not quantitative according to the different CP dynamics dominated by several factors including heteronuclear dipolar couplings, spin-lattice relaxation times in the rotating frame, molecular motions, number of around abundant spins, and so on. Over the years, numerous efforts have been made to obtain quantitative CP/MAS spectroscopy. This review firstly briefly illustrated the introduction of CP and CP dynamics, and then a series of quantitative NMR methods based on CP were introduced, including ramped-amplitude CP (RAMP-CP), multiple-contact CP, quantification of CP (QCP), Lee-Goldburg frequency modulated CP (LG-FMCP) and quantitative CP (QUCP).

Key words： solid state NMR; quantitative NMR; quantitative cross polarization; relaxation time

Cite this article

LIANG Li-xin , DENG Feng , HOU Guang-jin . Quantitative Cross Polarization Magic-Angle Spinning NMR Spectroscopy in Solids[J]. Chinese Journal of Magnetic Resonance, 2020 , 37(1) : 1 -15 . DOI: 10.11938/cjmr20192779

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