Chinese Journal of Magnetic Resonance >
Interactions Between n-Butanol/Propionic Acid and Humic Acid Studied by NMR Spectroscopy
Received date: 2021-02-28
Online published: 2021-03-31
The Fischer-Tropsch process produces liquid fuels. However, the process also yields Fischer-Tropsch wastewater, an acidic and corrosive byproduct enriched with various water-soluble oxygen-containing compounds such as alcohols, aldehydes, ketones and carboxylic acids, demanding careful treatment before discharge. Herein, the interactions between n-butanol and propionic acid, two main components in Fischer-Tropsch wastewater, and humic acid (HA) were studied with nuclear magnetic resonance (NMR) techniques. One-dimensional 1H chemical shift titration and 1H relaxation time measurements showed that: the peak width of both n-butanol and propionic acid broadened with increasing HA concentration, while the 1H chemical shift was unaltered for n-butanol, but moved to high field for propionic acid. The 1H spin-lattice and spin-spin relaxation time of n-butanol and propionic acid decreased and the 1H correlation time increased with increasing HA concentration. The interactions between HA and n-butanol were enhanced by increasing the HA concentration, but less affected by solution pH. While, the interactions between HA (20 mg/mL) and propionic acid were promoted by increasing the HA concentration and decreasing the solution pH value. It also appeared that the HA concentration plays a decisive role in the interaction. The study demonstrated that using HA for treatment of Fischer-Tropsch wastewater has a great potential in industrial applications owing to its simplicity and low price.
Shu-huai ZHANG , Hui MA , Zhao-hui GUO , Min-jun MA , Yan QIAO , Ying-xiong WANG . Interactions Between n-Butanol/Propionic Acid and Humic Acid Studied by NMR Spectroscopy[J]. Chinese Journal of Magnetic Resonance, 2021 , 38(3) : 301 -312 . DOI: 10.11938/cjmr20212893
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