Chinese Journal of Magnetic Resonance >

2015 , Vol. 32 >Issue 4: 699 - 706

DOI: https://doi.org/10.11938/cjmr20150415

Progresses in Matrixed Chromatographic NMR

  • HE Bao-jiang1 ,
  • XU Xiu-juan1 ,
  • YANG Wei-ping1 ,
  • ZHANG Wen-juan1 ,
  • WU Rui3 ,
  • HUANG Shao-hua2* ,
  • YANG Ying2 ,
  • BAI Zheng-wu3*
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  • 1. Zhengzhou Tobacco Institute of CNTC, Zhengzhou 450001, China;
    2. Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China;
    3. School of Chemical and Environment Engineering, Wuhan Institute of Technology, Wuhan 430073, China
*Corresponding author： HUANG Shao-hua, Tel: +86-532-80662660; E-mail: huangsh@qibebt.ac.cn; BAI Zheng-wu, Tel: +86-27-87195680; E-mail: zhengwu_bai@yahoo.com.

Received date: 2014-12-17

  Revised date: 2015-10-23

  Online published: 2015-12-05

Supported by

国家自然科学基金资助项目(21105108)

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Abstract

Diffusion ordered NMR spectroscopy (DOSY), sometimes also known as chromatographic NMR (CNMR), is a powerful tool for analyzing complex mixture. However, it is often difficult to distinguish components having similar molecular properties using only the diffusion characteristics. A practical way to solve this problem is adding some matrices, such as silica gel or polymers into magic angle spinning rotor or NMR tube, as the virtual stationary phase (VSP), to increase the difference in diffusion rate among different components. Matrix aided CNMR has been shown to have improved discriminating capability when analyzing complex mixtures. In this paper, recent progresses in the field of matrixed CNMR were reviewed.

Key words： DOSY; self-diffusion coefficient; matrix; chromatographic NMR

Cite this article

HE Bao-jiang1 , XU Xiu-juan1 , YANG Wei-ping1 , ZHANG Wen-juan1 , WU Rui3 , HUANG Shao-hua2* , YANG Ying2 , BAI Zheng-wu3* . Progresses in Matrixed Chromatographic NMR[J]. Chinese Journal of Magnetic Resonance, 2015 , 32(4) : 699 -706 . DOI: 10.11938/cjmr20150415

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