MAPbCl3钙钛矿中甲胺阳离子运动的固体2H NMR研究
梁佳琪,乔文成,姚叶锋

Solid-state 2H NMR Study of the Motion of CH3NH3+ in MAPbCl3 Perovskite
Jia-qi LIANG,Wen-cheng QIAO,Ye-feng YAO
图5 (a) MA的运动模型Ⅳ;(b)基于模型Ⅳ的拟合2H NMR谱.拟合过程中,Ω=80 kHz,θ值从50˚增加到60˚;(c)基于模型Ⅳ的拟合2H NMR谱.拟合过程中,θ=54.7˚,Ω值从50 kHz增加到110 kHz.为了使图更加清晰,MA中部分原子被省略
Fig.5 (a) The motion model Ⅳ of MA cation; (b) Simulated 2H NMR spectra based on the motion model Ⅳ. In the simulation, Ω is set to 80 kHz and θ varies from 50˚ to 60˚; (c) Simulated 2H NMR spectra based on the motion model Ⅳ. In the simulation, θ is set to 54.7˚ and Ω varies from 50 kHz to 110 kHz. Some atoms in the MA cation are omitted for clarity