可疑缴获物中苯乙基依托尼秦的结构解析

刘永红, 廖琦, 焦英, 孙卫, 肖雷, 贾薇, 刘翠梅

Structural Elucidation of Phenylethyl Etonitazene in Seized Powders

LIU Yonghong, LIAO Qi, JIAO Ying, SUN Wei, XIAO Lei, JIA Wei, LIU Cuimei

表2 苯乙基依托尼秦的 1H 和 13C NMR 归属（CD3OD）

Table 2 1H and 13C NMR data of the phenylethyl etonitazene (CD3OD)

Position δ C DEPT δ H (J/Hz) HSQC 1H -1H COSY 1H -1H TOCSY 1H -13C HMBC 2 160.2 C / / / / H-10, H-14, H-15 4 112.3 CH 8.68 (1H, d, 2.1) + / H-6, H-7 C-5, C-6, C-8, C-9 5 132.9 C / / / / H-4, H-7 6 122.5 CH 8.51 (1H, dd, 9.1, 2.1) + H-7 H-4, H-7 C-4, C-8, C-9 7 114.7 CH 8.29 (1H, d, 9.1) + H-6 H-4, H-6 C-4, C-5, C-9 8 136.8 C / / / / H-4, H-6, H-10 9 147.6 C / / / / H-4, H-6, H-7 10 40.9 CH2 4.96 (2H, t, 8.3) + H-11 H-11 C-2, C-8, C-11 11 50.0 CH2 3.43 (2H, t, 8.3) + H-10 H-10 C-10, C-12a, C-12b 12a 48.8 CH2 3.36 (4H, m) + H-13a H-13a, H-13b C-11, C-12b, C-13a 12b 48.8 CH2 3.36 (4H, m) + H-13b H-13a, H-13b C-11, C-12a, C-13b 13a 9.1 CH3 1.39 (6H, t, 7.3) + H-12a H-12a, H-12b C-12a 13b 9.1 CH3 1.39 (6H, t, 7.3) + H-12b H-12a, H-12b C-12b 14 29.7 CH2 3.65 (2H, t, 7.6) + H-15 H-15 C-2, C-15, C-16 15 33.0 CH2 3.27 (2H, t, 7.6) + H-14 H-14 C-2, C-14, C-17a, C-17b 16 131.6 C / / / / H-14, H-18a, H-18b 17a 130.7 CH 7.21 (2H, d, 8.6) + H-18a H-18a, H-18b C-15, C-17b, C-18a, C-19 17b 130.7 CH 7.21 (2H, d, 8.6) + H-18b H-18a, H-18b C-15, C-17a, C-18b, C-19 18a 116.0 CH 6.85 (2H, d, 8.6) + H-17a H-17a, H-17b C-16, C-18b, C-19 18b 116.0 CH 6.85 (2H, d, 8.6) + H-17b H-17a, H-17b C-16, C-18a, C-19 19 159.7 C / / / / H-17a, H-17b, H-18a, H-18b, H-20 20 64.5 CH2 3.98 (2H, q, 7.0) + H-21 H-21 C-19, C-21 21 15.1 CH3 1.35 (3H, t, 7.0) + H-20 H-20 C-20