氟醚菌酰胺波谱学数据全归属

易春海, 李芳, 杨晓云

Spectroscopic Data of Fluopimomide and Interpretations

YI Chunhai, LI Fang, YANG Xiaoyun

表1 氟醚菌酰胺核磁共振信号全归属

Table 1 The complete assignment of NMR spectroscopic data of fluopimomide

Position	δ_C(J/Hz)	δ_H(J/Hz)	HSQC	¹H-¹H COSY	HMBC
1	/	7.68 (s, 1H)	/	H-9	/
2	158.3	/	/	/	/
3	108.7 (t, J = 17.6 Hz)	/	/	/	/
4, 8	144.8 (dd, J = 251.4 Hz；17.6Hz)	/	/	/	/
5, 7	140.7 (dd, J = 265.7 Hz；15.4Hz)	/	/	/	H-15
6	140.2 (t, J = 11.0 Hz)	/	/	/	/
9	42.8	4.92 (s, 2H)	/	H-1	/
10	155.8	/	/	/	H-9, H-12, H-14
11	130.6	/	/	/	H-9, H-12
12	134.3 (q, J = 1.8 Hz)	7.98 (s, 1H)	+	H-14	H-14
13	127.0 (q, J = 33.8 Hz)	/	/	/	H12, H-14
14	143.4 (q, J = 1.6 Hz)	8.72 (s, 1H)	+	H-12	H-12
15	62.1	4.14 (s, 3H)	+	H-15	/
16	122.4 (q, J = 272.9 Hz)	/	/	/	H-12