Chinese Journal of Magnetic Resonance ›› 1985, Vol. 2 ›› Issue (2): 105-110.
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Mao Xian1, Shen Lianfang1, Ni Jiazhan2
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Abstract: Proton paramagnetic shifts of Ln(pic)3 (Ln=rare earth ions except Pin and Gd, pic=picric acid) hare been measured. The shift direction of the whole series shows a "tetrad effect". It can be well explained by the "tetrad rule" of 4f electron clouds. The configuration of Ln(pic)3 complex in acetone solution is discussed. The theory of pseudocontact shift is also discussed.
Mao Xian, Shen Lianfang, Ni Jiazhan. 1H NMR STUDY OF RARE-EARTH PICRATE COMPLEXES[J]. Chinese Journal of Magnetic Resonance, 1985, 2(2): 105-110.
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