Chinese Journal of Magnetic Resonance ›› 1985, Vol. 2 ›› Issue (2): 111-119.

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13C-NMR STUDIES OF BENZO-15-CROWN-5

Han Xiuwen1, Hu Jiehan1, Yang Zhenyun1, Li Gang2, Li Ming2   

  1. 1. Dalian Institute of Chemical Physics, Academia Sinica;
    2. Chemistry Department, Liaoning Petagogical University
  • Received:1984-10-06 Revised:1984-12-28 Published:1985-06-05 Online:2018-01-23

Abstract: The 13C-NMR and 1H-NMR spectra of nine benzo-15-crown-5 are recorded. Comibned with microanalyses, infrared, ultraviolet and mass spectroscopy data, the molecular structures of the crowns are determined. All the 13C-NMR spectral lines are assigned based on the line positions and splittings as well as substituent inductive effects. The influences of benzine ring's different sub-stituets on the chemical shifts of crown's carbons are also discussed.