Chinese Journal of Magnetic Resonance ›› 1987, Vol. 4 ›› Issue (2): 121-130.

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ESR STUDY OF SOME OXOVANDIUM ACIDIC PHOSPHATES (PHOSPHONATES) COMPLEXES IN CHLOROFORM

Chen Deyu1, Xu Yuanzhi1, Wang Shuyuan1, Zhou Chengming2   

  1. 1. Department of Chemistry, Zhejing University, Handzhou;
    2. Shanghai Institute of Organic Chemistry, Academia Sinica
  • Received:1986-09-18 Published:1987-06-05 Online:2018-01-22

Abstract: ESR spectra of some oxovanadium acidic phosphates (phosphonates) complexes in chloroform measured at room temperature were further analyzed. ESR spectral parameters of these complexes in chloroform at liquid nitrogen temperature were determined.Their bond parameters were calculated and the bonding character between vanadium (Ⅳ) and ligands is discussed in this paper.

Key words: acidic phosphates and phosphonates, oxovandium(Ⅱ)complexes, chloroform, ESR spectra