Chinese Journal of Magnetic Resonance ›› 1989, Vol. 6 ›› Issue (3): 318-325.

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STUDIES ON 13C NMR SPECTRA AND STRUCTURE OF LANTHANIDE COMPLEXES WITH L-HISTID

Chen Jianshe1, Shen Lianfang2, Xu Yuanzhi1, Yao Kemin1   

  1. 1. Department of Chemistry, Zhejiang University;
    2. Wuhan Institute of Physics, Academla Sinica
  • Received:1988-07-04 Revised:1988-10-21 Published:1989-09-05 Online:2018-01-22

Abstract: The paramagnetic induced shifts of the coordination compounds of lanthanide with L-histidinc have been measured in weak-acidic condition by XL-200 NMR spectrometer. The induced shifts were separated into compound formation shifts, contact shifts and pseudo-contact shifts. The structures of coordination compounds were simulated based on the pseudo-contact shifts and some structure parameters have thus been obtained. In addition, the magnetic characteristics of lanthanides were discussed in this paper.

Key words: Lanthanidc, L-histidine, 13C NMR spectrum