Chinese Journal of Magnetic Resonance ›› 1990, Vol. 7 ›› Issue (1): 115-118.

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TEMPERATURE-DEPENDENT 11B NMR STUDIES OF SODIUM BORATE GLASSES

Xu Shu, Pan Linzhang, Wu Xuewen   

  1. Department of Physics, East China Normal University, Shanghai
  • Received:1989-03-16 Revised:1989-06-17 Published:1990-03-05 Online:2018-01-23

Abstract: Temperature-dependent 11B NMR technics have been employed to determine the boron coordination in sodium borate glasses at room temperature and 300℃.The results show that, as R>0.5, the fraction of borons in 4-coordinated will decrease as temperature increases. These resuhs mean that it is possible for glass structure changes as temperature is below the transitional temperature.

Key words: Temperature-dependent NMR, Vitreous, Transitional temperature