Chinese Journal of Magnetic Resonance ›› 1991, Vol. 8 ›› Issue (2): 215-220.

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13C NMR STUDY OF THE PLATINUM (Ⅱ) COMPLEXES OF BIS (DIALKYLPHOSPHINO) ETHANE

Zhang An Jiang1, Jiang Qiongzhong2, Zhang Liangfu2   

  1. 1. School of Phannacy, West China University of Medical Sciences, Chengdu;
    2. Chengdu Institute of Organic Chemistry, Acadcmia Science
  • Received:1990-07-03 Revised:1990-10-06 Published:1991-06-05 Online:2018-01-20

Abstract: 13C NMR of a series of cis-Pt (diphos) X2 complexes was studied. The results showed that X ligand and R alkyl have considerable effect on the chemical shift of bridge carbon (C1). The existance of conformational isomers of some compounds was confirmed and the conformational characteristics of platinum complexes was discussed.

Key words: 13C NMR, Cis-Pt (diphos) X2, Conformation