TRANSITION-METAL COMPOUNDS WITH BIDENTATE LIGANDS Ⅲ. EPR Study on Vanadium 2-Mercaptophenolates

Chinese Journal of Magnetic Resonance ›› 1991, Vol. 8 ›› Issue (4): 365-370.

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TRANSITION-METAL COMPOUNDS WITH BIDENTATE LIGANDS Ⅲ. EPR Study on Vanadium 2-Mercaptophenolates

Weng Linghong¹, Liu Hanqin², Sun Qiongli¹, Huang Xin¹, Kang Beisheng¹

1. Fuzhou Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter;
2. Chinese Academy of Sciences, Fuzhou, Fujian 350002

Received:1990-12-10 Revised:1991-05-18 Published:1991-12-05 Online:2018-01-20
Supported by:
The project was supported by National Natural Science Foundation of China

Abstract

Abstract: Vanadium mercaptophenolate complexes (Ph₄P)[V₃(mp)₆] (I) and (Ph₄P)₂[NaV (mp)₃ (MeCN) (MeOH)]₂ (Ⅱ) are paramagnetic. Their EPR spectra were measured in solution or/and in polycrystalline form at both ambient and liquid nitrogen temperatures. The simulated spectra were computed with try-or-error values of g, A, and δ_w (half-line width) based on the computer program. The unpaired electrons are essentially localized around the vanadium atoms.

Key words: EPR, Vanadium (IV) complex, O-mercaptophenolate

Weng Linghong, Liu Hanqin, Sun Qiongli, Huang Xin, Kang Beisheng. TRANSITION-METAL COMPOUNDS WITH BIDENTATE LIGANDS Ⅲ. EPR Study on Vanadium 2-Mercaptophenolates[J]. Chinese Journal of Magnetic Resonance, 1991, 8(4): 365-370.

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TRANSITION-METAL COMPOUNDS WITH BIDENTATE LIGANDS Ⅲ. EPR Study on Vanadium 2-Mercaptophenolates

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