THECIDEP SPECTRUM OF PHOTOLIZIED P-BENZOSEMIQU1NONE RADICAL

Chinese Journal of Magnetic Resonance ›› 1992, Vol. 9 ›› Issue (3): 269-275.

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THECIDEP SPECTRUM OF PHOTOLIZIED P-BENZOSEMIQU1NONE RADICAL

Lu Tongxing, Zhao Xianzhang, He Guanglong, Wei Qizheng, Yu Qishan

Speotroscopy and Maternial Labocatory, Department of Physis, Aetumri Nernal University Wuhu 241000

Received:1991-07-24 Revised:1991-11-10 Published:1992-09-05 Online:2018-01-20

Abstract

Abstract: The CIDEP emission spectrom of P-benzosemiquinome radocal by photolysing P-benzoquinome was obtained experimentally with the highly time resolved ESR spectrometer.Using TM and RPM mechamisms,we invesigated the polarization of the radical and clculated the cahamcements V(I)=-0.66.and V(R)=0.2,the first order mention rate k_1,A=0.05/μs,the second order spin selective reaction mate β=0.02/μs,and the relaxation time T₁=T₂=2.3μs.

Key words: CIDEP, Time resolved ESR, Photolizrad radicel, P-benzosemiquinome radocal

Lu Tongxing, Zhao Xianzhang, He Guanglong, Wei Qizheng, Yu Qishan. THECIDEP SPECTRUM OF PHOTOLIZIED P-BENZOSEMIQU1NONE RADICAL[J]. Chinese Journal of Magnetic Resonance, 1992, 9(3): 269-275.

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THECIDEP SPECTRUM OF PHOTOLIZIED P-BENZOSEMIQU1NONE RADICAL

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