Chinese Journal of Magnetic Resonance ›› 1994, Vol. 11 ›› Issue (1): 27-33.

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DKTERMINATION OF INTERNUCLEAR DISTANCES FROM THE NONSYMMETRIC 2D NOESY METHOD 2.The Nonsymmetric 2D NOESY Experiment for Cis-Pt(NH3)2(Guo)2Cl2

Miao Xijia1,2, Han Xiuwen1, Hu Jiehan1   

  1. 1. Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023;
    2. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics, The Chinese Academy of Sciences, Wuhan 430071
  • Received:1992-06-25 Revised:1993-04-05 Published:1994-03-05 Online:2018-01-20

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Abstract: The nonsymmetric 2D NOESY experiment has been used to investigate the conformation of cis-platinum complex Pt(NH3)2(Guo)2Cl2 in deuterium aqueous solution. The results showed that the cyclic conformation of sugar for guanosine in Cis-Pt(NH3)2(Guo)2Cl2 changes obviously as guanosine coordinates toward platinum.

Key words: Nonsymmetric 2D NOESY, Internuclear distance, Solution conformation, Cis-platinum complex Pt (NH3)2(Guo)2Cl2

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