APPLICATION OF NEWLY-DEVELOPED 1H NMR TECHNIQUES TO THE STUDY OF HUMIC ACIDS

Chinese Journal of Magnetic Resonance ›› 1998, Vol. 15 ›› Issue (5): 411-420.

Previous Articles Next Articles

APPLICATION OF NEWLY-DEVELOPED ¹H NMR TECHNIQUES TO THE STUDY OF HUMIC ACIDS

Wang Liming¹, Mao Xi'an¹, Yang Yuhui²

1. Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, Wuhan 430071;
2. Department of Chemical Engineering, University of Cambridge, Pembroke Street, CB2 3RA, Cambridge, UK

Received:1998-03-26 Revised:1998-04-23 Published:1998-10-05 Online:2018-01-17

Abstract

Abstract: Some newly developed one and two dimensional ¹H NMR techniques, including totally correlated spectroscopy (TOCSY), self-diffusion coefficient measurements and maximum quantum spectroscopy (MAXY), are applied to the study of a humic acid sample suspended or dissolved in D₂O, NaOH/D₂O and DM SO-d₆.T OCSY experiments suggest that humic acids contain poly peptides that are soluble in DMSO but not in water, while the self-diffusion coefficient measurements suggest that in basic solution there are small molecules that are not included in the humic acid aggregates.From the MAXY spectra, detailed assignments for the proton resonances become possible.

Key words: Humicacids, ¹H NMR, TOCSY, Self-diffusion measurement, MAXY spectral editing

Wang Liming, Mao Xi'an, Yang Yuhui. APPLICATION OF NEWLY-DEVELOPED ¹H NMR TECHNIQUES TO THE STUDY OF HUMIC ACIDS[J]. Chinese Journal of Magnetic Resonance, 1998, 15(5): 411-420.

[1]	ZHAI Chonggang,WANG Pengcheng,SHAN Yubao,LAN Yu,HU Rui,YANG Yunhuang. Structure Characterization and Analgesic Activity of Novel Pyrazolo[3,4-d]pyrimidin-4-one Derivatives [J]. Chinese Journal of Magnetic Resonance, 2023, 40(1): 1-9.
[2]	Xiao-li CHEN,Tian-qiao YONG,Cheng CHEN,Juan FU,Jia-mei MO,Qiu-cheng SU. Physical and Chemical Properties of Silicone Electrolyte Materials Evaluated by Nuclear Magnetic Resonance Technology [J]. Chinese Journal of Magnetic Resonance, 2021, 38(3): 291-300.
[3]	Lei JIANG,Yang FU,Wen-wen GUO,Guo ZHENG,Qiang WANG. Nuclear Magnetic Resonance Assignment and Crystal Structure of 3, 22-Dihydroxyhopane [J]. Chinese Journal of Magnetic Resonance, 2021, 38(2): 255-267.
[4]	Meng-yu DOU,Qi ZHAO,Xiang-lin HOU,Lei LIU,Ming-xing TANG,Ying-xiong WANG. Structural Elucidation and Quantitative Analysis of Hydrogenation Products of Anthracene by NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2021, 38(2): 239-248.
[5]	Xiao-li CHEN,Wei LV,Qiu-cheng SU,Juan FU,Jia-mei MO,Qi-ying LIU. Conversion of Lignocellulose Studied by Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2021, 38(2): 277-290.
[6]	ZHANG Fen-fen, SHEN Wen-bin, XU Kai-bing, YANG Ming. A Proton Nuclear Magnetic Resonance Method for Quantitative Analysis of Ticagrelor [J]. Chinese Journal of Magnetic Resonance, 2020, 37(2): 216-223.
[7]	XIAO Xiong-jie, HU Mary, ZHANG Xu, HU Jian-zhi. An NMR-Based Metabolomics Study of Kidneys from Mice Exposed to Ionizing Radiation [J]. Chinese Journal of Magnetic Resonance, 2019, 36(2): 172-181.
[8]	WANG Shuang-hong, ZENG Pei, PAN Si-na, WANG Jia, WANG Shu-mei, YANG Yong-xia. Effects of Gegen Qinlian Decoction on the Fecal Metabonome of High Fructose-Induced Insulin Resistance Rats Studied by ¹H NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2019, 36(2): 182-194.
[9]	TANG Ming-xue, SCHMIDT Claudia. Estimation of Nematic Order Parameters via Haller Analysis of ¹H NMR Spectra of Liquid Crystals [J]. Chinese Journal of Magnetic Resonance, 2019, 36(2): 138-147.
[10]	WU Jin-ze, XIN Jia-xiang, FU Xiao-bin, YAO Ye-feng. A Wide-Line Solid-State ¹H NMR Study of Phase Structures of Semi-Crystalline Polymers [J]. Chinese Journal of Magnetic Resonance, 2019, 36(1): 23-33.
[11]	ZHAO Hong-bo, CHAI Xiao-fei, WANG Yue-hua, SHI Hui-bing, ZHANG Rui, DONG Zhao-ping, HAN Li-xia. Analysis of Styrene-Butadiene-Styrene (SBS) Content in Modified Asphalt with ¹H NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2017, 34(3): 323-328.
[12]	CAO Chao-tun, LUO Qing-qing, CAO Chen-zhong. Substituent Effects on the ¹H NMR Chemical Shifts of CH=N(O) Bridge Group in Diaryl Nitrone [J]. Chinese Journal of Magnetic Resonance, 2017, 34(1): 69-77.
[13]	GUO Qiang-sheng, LIU Ming-ke, YU Shan, SHEN Ting-ting, SONG Wei, XU Xu. A Quantitative NMR Method to Analyze Vitamin B1, Vitamin B2, Nicotinamide and Calcium Pantothenate Contents in Compound Vitamin B Tablets [J]. Chinese Journal of Magnetic Resonance, 2016, 33(3): 442-451.
[14]	ZHOU Qiu-ju, XIANG Jun-feng, TANG Ya-lin, CUI Jie, WU Ning-ning. Pure Shift Proton NMR Spectroscopy and Its Applications [J]. Chinese Journal of Magnetic Resonance, 2016, 33(3): 502-513.
[15]	ZHENG Jin, XUE Hui-yun, LIN Cai-feng, LIN De-xun, LU Jia, YANG Hui, WANG Xiang-peng, ZOU You-si. Dating Oily Ballpoint Pen Hand-Writings by ¹H NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2016, 33(2): 198-207.

APPLICATION OF NEWLY-DEVELOPED ¹H NMR TECHNIQUES TO THE STUDY OF HUMIC ACIDS

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments