PHOTOCATALYSIS OF HYPOCRELLIN (HB) IN THE ELECTRON TRANSFER REACTION OF C60 AND TRIETHYLAMINE

Chinese Journal of Magnetic Resonance ›› 1999, Vol. 16 ›› Issue (4): 319-322.

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PHOTOCATALYSIS OF HYPOCRELLIN (HB) IN THE ELECTRON TRANSFER REACTION OF C₆₀ AND TRIETHYLAMINE

Sun Jian¹, Liu Yang¹, Chen Dewen¹, Zhang Qiyuan¹, An Jingyi²

1. Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080;
2. Institute of Photographic chemistry, The Chinese Academy of Sciences, Beijing 100101

Received:1999-01-15 Revised:1999-04-09 Published:1999-08-05 Online:2018-01-11

Abstract

Abstract: ESR technique was used to investigate intermolecular electron transfer reaction between C₆₀ and triethylamine (Et₃N). Photocatalysis of hypocrellin (HB) for the above electron transfer reaction was also discussed in this paper. Intermediates produced in the electron transfer reaction system of Et₃N/C₆₀/HB were directly confirmed by ESR method. The experimental results illustrated that HB acted as a photocatalyst and electron transfer reaction from Et₃N to ground state C₆₀ at room temperature could be realized through two-step electron transfer pathway.

Key words: ESR, C₆₀, Hypocrellin B, Electron transfer reaction

Sun Jian, Liu Yang, Chen Dewen, Zhang Qiyuan, An Jingyi. PHOTOCATALYSIS OF HYPOCRELLIN (HB) IN THE ELECTRON TRANSFER REACTION OF C₆₀ AND TRIETHYLAMINE[J]. Chinese Journal of Magnetic Resonance, 1999, 16(4): 319-322.

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PHOTOCATALYSIS OF HYPOCRELLIN (HB) IN THE ELECTRON TRANSFER REACTION OF C₆₀ AND TRIETHYLAMINE

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