Chinese Journal of Magnetic Resonance ›› 2000, Vol. 17 ›› Issue (4): 305-308.

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AN EPR STUDY OF THE QUINONE-RHODIUM PHOSPHINE ORGANOMETALLIC COMPLEX

LI Cong1,2, FENG Liangbo1, WANG Hanqing1   

  1. 1. Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou 730000;
    2. Experiment Center of Yunnan University, Kunming 650091
  • Received:1999-10-18 Published:2000-08-05 Online:2018-01-11

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Abstract: The two stable DTBQ-RhCOCl(PPh3)2 and DTBQ-RhCl(PPh3)3 organometallic radical complexes are prepared by oxidative addition reactions. EPR observations provide insights into the radical structures and the possible electron transfer processes.

Key words: DTBQ-RhCOCl (PPh3)2, DTBQ-RhCl (PPh3)3, Electron transfer processes, Organometallic radical complex

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