Chinese Journal of Magnetic Resonance

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NMR RESEARCH ON TRITERPENOID SAPONINS LATIFOLOSIDE I AND KUDINOSIDE K

OUYANG Ming-an1, TENG Rong-wei2, WANG De-zu2, YANG Chong-ren2
  

  1. 1.Department of Chemistry, Huaqiao University, Quanzhou 362000;
    2.Kunming Institute of Botany, The Chinese Academic of Sciences, Kunming 650204
  • Received:2001-04-02 Revised:2001-04-10 Published:2001-06-05 Online:2001-06-05
  • Supported by:

    中国科学院昆明植物研究所植物化学开放研究室资助项目.

Abstract:

This paper discussed the structure elucidation of two saponins, Latifoloside I isolated from Ilex latifolia Thunb and Kudinoside K isolated from Ilex
kudincha C. J. Tseng. On the basis of chemical and spectroscopic evidences, mainly modern 2D NMR technique, their structures were determined to be 3-O-β-D-glucopyranosyl-(1→3)-α-L-arabinopyranosyl-30(S)-3,19,23-trihydro-xyurs-12-en-28-oic- acid 28-O-β-D-glucopyranoside and 3-O-[α-L-rhamnopyranosyl-(1→2)]-[β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl-(1→3)]-α-L-arabinopyranoyl-3β,19α,20β-trihydr-oxyurs-12-en-28-oic acid 28-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, respectively.

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