Chinese Journal of Magnetic Resonance

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APPLICATION OF NMR IN STUDYING THE MECHANISM OF CHEMICAL REACTIONS INVOLVING FLUORINE -CONTAINING LACTONES

ZHOU Li-fang1,PAN Tie-ying1,SHI Xin-mei1,HE Cai-xia1,ZOU Xiao-wei2,WU Fan-hong2   

  1. 1.Analysis and Reserch Center, East China University of Science and Technology, S hanghai  200237, China; 2.Institute of Fine Chemistry, East China University of Science and Techno logy, Shanghai  200237, China
  • Received:2002-04-28 Revised:2002-06-10 Published:2002-12-05 Online:2002-12-05

Abstract:

The fluorine-containing lactones are often present in natural organic- compounds. In this study the structures of three fluorine-containing lactones were determined using the NMR techniques(1H NMR,13C NMR,1H -1H COSY,NOESY,HMB C,HMQC). Two-dimensional NOESY was especially useful for providing information on the stereo configuration of the compounds. Knowing the structures can be help ful in studying the mechanism of chemical reactions involving fluorine-containi ng lactones.

Key words: NMR spectroscopy, fluorine-containing lactones, stereo configuration

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