Chinese Journal of Magnetic Resonance ›› 1985, Vol. 2 ›› Issue (1): 25-30.

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THE NMR STUDY OF METALLIC NUCLEI I THE 111Cd,113Cd,117Sn,119Sn,199Hg NMR SPECTRA OF METALLIC COMPLEXES

Yang Zhenyun, Han Xiuwen, Hu Jiehan, Ji Tao   

  1. Dalian Institute of Chemical Physics, Academia Sinica
  • Received:1984-09-05 Published:1985-03-05 Online:2018-01-23

Abstract: The 111Cd,113Cd,117Sn,119Sn,199Hg NMR spectra of metallic complexes MPy2M(bi-Py)Cl2, M(o-Phen)Cl2 (M=Cd, Sn, Hg) have been recorded directly using FT-NMR spectrometer. The influences of solvent, concentration and temperature on the chemical shifts of the spectra are investigated,The variations of the spectral parameters with the molecular structures as well as primary isotope shielding effects are discussed.