Chinese Journal of Magnetic Resonance ›› 1993, Vol. 10 ›› Issue (1): 17-24.

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SPECTRAL CHARACTERIZATION OF HETEROCYCLIC ORGANOTIN(Ⅳ) COMPOUNDS

Hu Xinquan, Wang Shihua, Yan Shenggang, Yu Zhengkun   

  1. Dalian Institute of Chemical Physics. Chinese Academy of Sciences, Dalian, Liaoning 116023, China
  • Received:1992-01-25 Revised:1992-09-04 Published:1993-03-05 Online:2018-01-20

Abstract: Eight heterocyclic aryl n-butyltin (Ⅳ) compounds are synthesized. The general formula is Rn-SnBu(4-n)(R=2-furyl or 2-thienyl, n=l,2,3; R=2-(N-methyl) pyrrolyl or 2-pyridyl, n=l). Four of them are novel compounds:dibutyl di(2-furyl) tin, butyltri (2-furyl)tin, dibutyl di(2-thienyl) tin and butyl tri(2-thicnyl) tin. Their structures are characterized by elementary analysis, IR and NMR etc. The spectral features are discussed.

Key words: Heteroaryl organotin, 119Sn NMR, 13C NMR