ONE-DIMENSIONAL DETECTION OF HIGHER-ORDER MULTIPLE QUANTUM TRANSITIONS BY RAMAN MAGNETIC RESONANCE

Chinese Journal of Magnetic Resonance ›› 1999, Vol. 16 ›› Issue (6): 505-511.

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ONE-DIMENSIONAL DETECTION OF HIGHER-ORDER MULTIPLE QUANTUM TRANSITIONS BY RAMAN MAGNETIC RESONANCE

ZHOU Zhifa^1,2, MIAO Xijia¹, HUANG Yongren², YE Chaohui¹

1. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, Wuhan 430071;
2. NMR Lab., Analytical Center, East Normal Universityt Shanghai 200062

Received:1999-04-07 Revised:1999-09-03 Published:1999-12-05 Online:2018-01-13

Abstract

Abstract: Raman Magnetic Resonance (RMR) spectroscopy for a heteronuclear AX₃ spin system isrecorded by perturbing the highest-order quantum coherence state. The RMR experimentshows that an effective way for detecting higher-order quantum transitions is to prepare thehigher-order multiple quantum (MQ) coherence in the initial state. The product operatorformalism provides an exact method to predict arbitrary order MQ frequencies and intensitiesof RMR spectroscopy. By means of accumulation of Positive-negative alternate offset, thestrong single quantum signals are suppressed and hence the MQ transition signals can be detected with a higher efficiency.

Key words: NMR, Raman Magnetic Resonance, MQ Coherence, Product Operator Formalism, Heteronuclear AX₃ Spin System

ZHOU Zhifa, MIAO Xijia, HUANG Yongren, YE Chaohui. ONE-DIMENSIONAL DETECTION OF HIGHER-ORDER MULTIPLE QUANTUM TRANSITIONS BY RAMAN MAGNETIC RESONANCE[J]. Chinese Journal of Magnetic Resonance, 1999, 16(6): 505-511.

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ONE-DIMENSIONAL DETECTION OF HIGHER-ORDER MULTIPLE QUANTUM TRANSITIONS BY RAMAN MAGNETIC RESONANCE

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