Chinese Journal of Magnetic Resonance ›› 1989, Vol. 6 ›› Issue (1): 111-114.

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1H-NMR STUDIES OF SOME Fe-Mo (W)-S DEMETALLIC COMPOUNDS

Wu Daxu, Gou Zhi, Liu Hanqin   

  1. Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou, Fujian
  • Received:1987-12-12 Revised:1988-03-08 Published:1989-03-05 Online:2018-01-22

Abstract: Six dimetallic compounds (Et4N)2((PhS)2FeS2MS2-nOn (M=Mo,W; n=0, 1, 2) were studied by 1H-NMR. These results indicate that the isotropic shift is dominantly from contact interaction. Its magnitudes are correlated closely with Fe→M charge transfer which relies on the type of metal M and ite environment.

Key words: NMR, Mossbauer