THE STUDY ON NMR AND STEREOCHEMISTRY OF THE INTERMEDIATES OF 1-0-ALKYL ETHERS OF PHOSPHATIDYL CHOLINE (AEPC)

Chinese Journal of Magnetic Resonance ›› 1988, Vol. 5 ›› Issue (1): 31-36.

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THE STUDY ON NMR AND STEREOCHEMISTRY OF THE INTERMEDIATES OF 1-0-ALKYL ETHERS OF PHOSPHATIDYL CHOLINE (AEPC)

Peng Shiqi, Wang Dong, Huang Heqing, Cai Mengshen

Beijing Medical University, Beijing

Received:1987-04-10 Revised:1987-05-16 Published:1988-03-05 Online:2018-01-22

Abstract

Abstract: 1,3-Benzylideneglycerol and 1,2-benzylideneglycerol were obtained by the reaction of glycerine and benzaldehyde. 1,3-Benzylideneglycerol reacted with benzyl chloride and the products of the benzylation were 1,3-benzylideneglycerol benzyl ethers. All of these compounds are the important intermediates of AEPC. Their configurations were assigned based on the ¹H NMR. The existance of con-formational isomers in 1,3-benzylideneglycerol was confirmed. The conversion of configurations and conformations of these compounds in CDCl₃ is also reported here.

Key words: 1,3-Benzylideneglycerol, NMR, Configuration, Conformation

Peng Shiqi, Wang Dong, Huang Heqing, Cai Mengshen. THE STUDY ON NMR AND STEREOCHEMISTRY OF THE INTERMEDIATES OF 1-0-ALKYL ETHERS OF PHOSPHATIDYL CHOLINE (AEPC)[J]. Chinese Journal of Magnetic Resonance, 1988, 5(1): 31-36.

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THE STUDY ON NMR AND STEREOCHEMISTRY OF THE INTERMEDIATES OF 1-0-ALKYL ETHERS OF PHOSPHATIDYL CHOLINE (AEPC)

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