13C AND 119Sn NMR STUDY OF TRICYCLOHEXYLTIN (Ⅳ) CARBOXYLATES

Chinese Journal of Magnetic Resonance ›› 1990, Vol. 7 ›› Issue (1): 101-108.

Previous Articles Next Articles

¹³C AND ¹¹⁹Sn NMR STUDY OF TRICYCLOHEXYLTIN (Ⅳ) CARBOXYLATES

Zhang Diankun¹, Xie Qinglan¹, Zheng Jianyu¹, Li Jing¹, Li Songlan²

1. Institute of Elemento-organic Chemistry, Nankai University, Tian Jin;
2. The chemistry department, Nankai University, Tain Jin

Received:1988-11-12 Revised:1989-03-21 Published:1990-03-05 Online:2018-01-23

Abstract

Abstract: The ¹³C and ¹¹⁹Sn NMR spectra of CDCl₃ solutions of aliphatic and aromatic tricyclohexyltin (IV) carboxylates have been recorded. The chemical shifts (δ¹¹⁹Sn) and the coupling constants ¹J (¹³C, ¹¹⁹Sn) depend markedly on the coordination number of the tin atom. The chemical shifts and coupling constants ¹J (¹³C,¹¹⁹Sn) for aliphatic tricyclohexyltin (IV) carboxylates are in the range 6-11 ppm and 341-345 Hz, for aromatic tricyclohexyltin (IV) carboxylates are in the range 10 to 40 ppm and 310-340Hz, which provide evidence that the compounds are monomeric species in the solutions irrespective of their structure in the solid state.

Key words: Tricyclohexyltin (Ⅳ) carboxylate, NMR spectrum, Correlation

Zhang Diankun, Xie Qinglan, Zheng Jianyu, Li Jing, Li Songlan. ¹³C AND ¹¹⁹Sn NMR STUDY OF TRICYCLOHEXYLTIN (Ⅳ) CARBOXYLATES[J]. Chinese Journal of Magnetic Resonance, 1990, 7(1): 101-108.

[1]	GUO Jiangfeng,MACMILLAN Bryce,BALCOM Bruce. Insights into the Phase Structure and Dynamics of Polyurethane Rubber Using T₁-T₂^*Relaxation Correlation [J]. Chinese Journal of Magnetic Resonance, 2023, 40(2): 111-121.
[2]	HUANG Shan-shan, YAO Ye-feng, LI Peng, HE Pei-zhong. Quantum Chemical Calculation and Simulation of HSQC Experiments in Liquid-State NMR [J]. Chinese Journal of Magnetic Resonance, 2021, 38(1): 32-42.
[3]	FENG Zong-jing, DU Ya-ping, LUO Feng, XU Jun. An Ultrawide-Line ¹³⁹La Solid-State NMR Investigation of Layered La(OH)₂NO₃ [J]. Chinese Journal of Magnetic Resonance, 2020, 37(1): 76-85.
[4]	CHANG Xiao, SU Guan-qun, NIE Sheng-dong. Wavelet Transform-Based Signal Denoising in Low-Field NMR [J]. Chinese Journal of Magnetic Resonance, 2018, 35(3): 393-406.
[5]	YAN Xiao-jing, HU Bing-wen. Probing ¹⁵N-¹⁵N Correlations in g-C₃N₄ Samples with Solid-State NMR SHA+ Pulse Sequence [J]. Chinese Journal of Magnetic Resonance, 2016, 33(3): 361-367.
[6]	HU Hao，WEI Zhi-liang，LIN Liang-jie，SUN Hui-jun，LIN Yan-qin，CHEN Zhong. A Selective Encoding Method for Ultrafast Magnetic Resonance Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2015, 32(4): 563-573.
[7]	MAO Yun-zhi*，GUO Hua-min. Processing and Identifying NQR Signals in Explosive Detection [J]. Chinese Journal of Magnetic Resonance, 2014, 31(3): 381-388.
[8]	DENG Yi-bin；JI Dan；ZHOU Ping*. Application of Magnetic Resonance Methods in the Structural and Functional Characterization of Silk Fibroin [J]. Chinese Journal of Magnetic Resonance, 2008, 25(4): 555-571.
[9]	LI Zhao1,2， ZHU Hang1,2，CHENG Peng1,2，ZHOU Zhi-ming1,2，LIU Mai-li1，ZHANG Xu1*. HR-MAS ¹H NMR Spectra of Rat Kidney Tissue Analyzed by Statistical Total Correlation Spectroscopy (STOCSY) [J]. Chinese Journal of Magnetic Resonance, 2007, 24(4): 510-518.
[10]	LI Yong, SHAO Meng, WANG Qi, HOU Bi-Hui. TWO DIMENSIONAL CONTINUOUS-WAVE ELECTRON SPIN RESONANCE SPECTROSCOPY [J]. Chinese Journal of Magnetic Resonance, 2004, 21(1): 17-23.
[11]	ZHOU Ping1*, AU-YEUNG Steve C. F.2. DETERMINATION OF ROTATIONAL REORIENTATION CORRELATION TIME AND ⁵⁹Co NUCLEAR QUADRUPOLAR COUPLING CONSTANT OF POLYAMMONIUM MACROCYCLIC COBALTICYANIDE SUPERCOMPLEXES IN DILUTE AQUEOUS SOLUTIONS——An Application of Dynamic Laser Light Scattering Method [J]. Chinese Journal of Magnetic Resonance, 2003, 20(4): 319-328.
[12]	LI Yong-jian, WAN Jian, ZHAN Chang-guo*. A THEORETICAL STUDY ON C-H NUCLEAR SPIN-SPIN COUPLING CONSTANTS [J]. Chinese Journal of Magnetic Resonance, 2003, 20(3): 225-230.
[13]	CHEN Qi-ting, YUAN Xiao-yan, CAO Chen-zhong, LIU Shu-shen, LIU Hailing, LI Zhi-liang. ON PRELIMINARY APPROACH TO ESTIMATION AND PREDICTION OF CHEMICAL SHIFT OF CARBON-13 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY IN ALKANES BASED ON A NOVEL ATOMIC DISTANCE-EDGE VECTOR (MDE OR ν) [J]. Chinese Journal of Magnetic Resonance, 2001, 18(2): 175-185.
[14]	OUYANG Ming-an1, TENG Rong-wei2, WANG De-zu2, YANG Chong-ren2. NMR RESEARCH ON TRITERPENOID SAPONINS LATIFOLOSIDE I AND KUDINOSIDE K [J]. Chinese Journal of Magnetic Resonance, 2001, 18(2): 155-160.
[15]	DING Keyang. ACCURATE MEASUREMENTS OF HETERONUCLEAR ³¹P-¹H AND ³¹P-¹³C COUPLING CONSTANTS IN FRUCTOSE 1,6 DIPHOSPHATE ANION FROM E.COSY TYPE ³¹P-¹HCORRELATION SPECTRA [J]. Chinese Journal of Magnetic Resonance, 2000, 17(4): 271-276,282.

¹³C AND ¹¹⁹Sn NMR STUDY OF TRICYCLOHEXYLTIN (Ⅳ) CARBOXYLATES

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments