Chinese Journal of Magnetic Resonance ›› 1995, Vol. 12 ›› Issue (1): 13-21.

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STUDIES ON THE NUCLEAR MA GNETIC RESONANCE OF MOLYBDENUM (TUNGSTEN)-COPPER-SULPHUR-DIALKYLDI-THIOCARBAMATE CLUSTER COMPOUNDS

Cao Rong, Wu Daxu, Xie Xiulan, Hong Maochun, Jiang Feilong, Liu Hanqin   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002, and State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics, The Chinese Academy of Sciences, Wuhan 430071
  • Received:1994-03-08 Revised:2009-05-09 Published:1995-02-05 Online:2018-01-17

Abstract: A series of Molybdenum (Tungsten)-Copper-Sulphur-Dialkyldithiocarbamate of cluster compounds have been studied by 1H, 13C,and 95Mo NMR techniques, Several reactions of MoOnS4-n2-(n=0,2), CuCl, R2dtc(R2=Me2Et2) were monitored by dgnamic 95Mo NMR and the synthetic reaction scheme of the compounds are deduced on the dynamic data.

Key words: NMR, Dialkyldithiocarbamate, Mo(W)-Cu-S of cluster compounds, Reaction mechanism