Chinese Journal of Magnetic Resonance ›› 1998, Vol. 15 ›› Issue (5): 457-460.

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NMR STUDIES OF METALMACROCYCLIC COMPLEXES CONTAINING CRYPTAND N8O6

Wu Daxu, Yu Shuyan   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou 350002
  • Received:1998-03-10 Revised:1998-05-12 Published:1998-10-05 Online:2018-01-17

Abstract: 1H, 13C and HMQC NMR spectra of hetero-metal Ag-Na and homo-metal Cu cryptates with cryptand N8O6, [Ag2NaL] (ClO4)3(1) and [Cu2L](BF4)(ClO4)*DMF*0.5EtOH(2) have been determined at room temperature in solution.All resonances of the proton and carbon of the complexes were assig ned.The solution coo rdination behavior of the complexes were studied by 1H NMR spectra.

Key words: Cryptand N8O6, Ag-Na complex, Cu complex, NMR