Chinese Journal of Magnetic Resonance ›› 2000, Vol. 17 ›› Issue (2): 95-102.

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INVERSION RECOVERY MEASUREMENTS: THE RADIATION DAMPING EFFECTS

LUO Huijun, WANG Fu, ZHU Peifen, PAN Tieying, SHI Xinmei   

  1. Analysis and Research Center, East China University of Science and Technology, Shanghai, 200237
  • Received:1999-12-21 Revised:2000-01-04 Published:2000-04-05 Online:2018-01-11

Abstract: In the presence of strong radiation damping, the conventional two-pulse inversion recovery measurements have been performed on water sample(90%H2O/10%D2O). It shows that if two pulses in IR sequence are 180° out of phase and the flip angle of the inversion pule is smaller than 180°, or if two pulses are in phase and the flip angle of the inversion pulse is larger than 180°, the signal intensity will continuously changes with the recovery time. Conversely, if two pulses are in phase (or 180° out of phase) and the flip angle of the inversion pulse is smaller than 180° (or larger than 180°), the signal intensity will jump from the negative maximum to the positive maximum around τ=Trdln{tan[(π±δ)/2]}. Under the off-resonance condition, no matter what pulse phase, the beating effect can be always observed, but the phase of the signal explicitly depends on the relative phase of the pulses. As a result, the phase cycling will greatly suppress the beating effect. These phenomena can be well explained by the radiation damping theory. In addition, when the magnetization locates near the-zaxis during the detection, the deviation of theoretical expectation from the experimental data is closely related to the longitudinal relaxation effect.

Key words: NMR, Inversion recovery, Radiation damping, T1 relaxation, Signal intensity