SYNTHESIS AND CHARACTERIZATION OF Cu(Ⅱ) AND Zn(Ⅱ) COMPLEXES WITH NONCYCLIC POLYETHER SCHIFF BASES

Chinese Journal of Magnetic Resonance ›› 1998, Vol. 15 ›› Issue (4): 335-341.

Previous Articles Next Articles

SYNTHESIS AND CHARACTERIZATION OF Cu(Ⅱ) AND Zn(Ⅱ) COMPLEXES WITH NONCYCLIC POLYETHER SCHIFF BASES

Wu Jing¹, Yao Kemin¹, Shen Lianfang², Yuan Hanzhen²

1. Department of Chemistry, Zhejang University, Hangzhou 310027, China;
3. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Phys. & Math., The Chinese Academy of Sciences, Wuhan 430071, China

Received:1998-02-19 Revised:1998-04-21 Published:1998-08-05 Online:2018-01-13
Supported by:
Project supported by the National Natural Science Foundation of China(29671026), the Natural Science Foundation of Zhejiang Province (296062) and the state key Laboratory of MRAMP(971502)

Abstract

Abstract: Two kinds of noncyclic polyether Schiff bases, bis-salicylidene diethylene glycol diamine (SALDA)^[1] and bis salicylidene tetraethylene glycol diamine (SALTTA)^[2] as well as their new complexes[Zn(SALDA)] (NO₃)₂·4H₂O and Cu₃(SALTTA)(NO₃)₄ (NO₃)₂·3H₂O have been synthesized and characterized by IR and UV spectra, especially by ¹H and ¹³C NMR methods. Synthesis method has been studied in detail. IR spectra show that not all of the ethereal oxygen donor atoms in SALTTA are coordinated to the central metalions.

Key words: Non-cyclic polyether, Schiff base complex, Synthesis, IR, NMR

Wu Jing, Yao Kemin, Shen Lianfang, Yuan Hanzhen. SYNTHESIS AND CHARACTERIZATION OF Cu(Ⅱ) AND Zn(Ⅱ) COMPLEXES WITH NONCYCLIC POLYETHER SCHIFF BASES[J]. Chinese Journal of Magnetic Resonance, 1998, 15(4): 335-341.

[1]	KOU Xinhui, ZHANG Yubing. Study on the Enantiomeric Recognition of Chiral Ureas Containing Amino Acid Units [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 221-230.
[2]	DU Qunjie. Experimental Study on Accurate Determination of Shale Porosity by Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 275-284.
[3]	JIANG Chaochao, YAO Shouquan, XU Juncheng, JIANG Yu. Design of the Broadband Magnetic Resonance Microcoil [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 299-307.
[4]	LI Keyan, CHENG Xin, CHEN Junfei, CAO Li, HUANG Zhen, LIU Chaoyang. Development of Low-noise Preamplifier for Low-field NMR [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 321-333.
[5]	LI Yujiang, ZHAO Wei, TAO Le, LU Bohua, ZHENG Guo, ZHANG Haiyan, GUO Xiaohe, ZHAO Tianzeng. NMR Data Analysis of Acarbose [J]. Chinese Journal of Magnetic Resonance, 2025, 42(2): 184-194.
[6]	ZHANG Jiayu, NIE Wenbo, TU Zhao, ZHENG Limin, WANG Yan, YANG Chunsheng. Three-Dimensional Structures of 3/4/5-O-feruloylquinic Acids by NMR Spectroscopy and Quantum Chemistry Calculation [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 47-55.
[7]	SHEN Xueyuan, WANG Ruichen, QI Guodong, XU Jun, DENG Feng. Design of in situ Solid-State NMR Rotor Inserts and Their Application to Catalytic Reactions [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 13-21.
[8]	SHEN Zhiqiang, DENG Yabo, YANG Peiju, HU Xiaoxue, HUANG Xiaojuan, XU Chuanzhi, SONG Huanling. Design and Application of an in situ NMR Device for Light-Induced Reaction Systems [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 22-33.
[9]	LIU Hongbing, LIU Huili, LUO Liting, SUN Lijuan, CHEN Lei. Identification and Structural Characterization of an Unknown Trace Degradation Impurity in Cabazitaxel Injection by LC-DAD-SPE-NMR/MS [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 34-46.
[10]	LI Mingdao, YAO Shouquan, XU Juncheng, LV Xinglong, HE Fengcheng, JIANG Yu. Design of the Handheld NMR Console [J]. Chinese Journal of Magnetic Resonance, 2024, 41(3): 257-265.
[11]	WANG Xingle, SHAO Zhengze, DONG Hongchun, WEI Daxiu, CHEN Qun, YAO Yefeng. Studies on the ¹H NMR Spectral Features of Hydrogen Molecules in the Interstices of SiO₂ Particles [J]. Chinese Journal of Magnetic Resonance, 2024, 41(3): 315-321.
[12]	WANG Xia, WANG Yong, LAN Qing. Time-varying Analysis of Brain Networks Based on High-order Dynamic Functional Connections in Mild Cognitive Impairment [J]. Chinese Journal of Magnetic Resonance, 2024, 41(3): 286-303.
[13]	YANG Yu, CHEN Bo, WU Liubin, LIN Enping, HUANG Yuqing, CHEN Zhong. Spectrum Reconstruction for Laplace NMR: From Handcraft Regularization to Deep Learning [J]. Chinese Journal of Magnetic Resonance, 2024, 41(2): 191-208.
[14]	MA Yingying, ZHANG Gong, LIAO Zhongshu. A Method for Improving the Measurement Accuracy of Nuclear Magnetic Resonance Fast Relaxation Signal [J]. Chinese Journal of Magnetic Resonance, 2024, 41(2): 162-172.
[15]	ZHU Xiaofeng, ZHAO Zhihong, TAN Rui, ZHOU Long, WANG Yichuan, LIU Wenjing, ZHANG Minghui, LIU Huabing. Water Migration Characteristics of Pinus Sylvestris During the Drying Process Studied by Single-sided Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2024, 41(2): 173-183.

SYNTHESIS AND CHARACTERIZATION OF Cu(Ⅱ) AND Zn(Ⅱ) COMPLEXES WITH NONCYCLIC POLYETHER SCHIFF BASES

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments