NMR INVESTIGATION OF THE STRUCTURE OF NASICON TYPE COMPOUNDS

Chinese Journal of Magnetic Resonance ›› 1992, Vol. 9 ›› Issue (1): 75-80.

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NMR INVESTIGATION OF THE STRUCTURE OF NASICON TYPE COMPOUNDS

Yue Yong¹, Li Liyun¹, Zhou Fengqi², Pang Wenqin²

1. Laboratory of Magn. Rcson. and Atomic and Mol. Phys. Wuhan Inst. of Phys., the Chinese Academy of Sciences, 430071;
2. Department of Chemistry, Jilin University

Received:1991-03-18 Revised:1991-06-03 Published:1992-03-05 Online:2018-01-20

Abstract

Abstract: The structure of several NASICON compounds prepared by hydrothermal crystallization were studied by solid -state high-resolution ³¹P and ²⁹Si MAS NMR. The state and distribution of phosphorus and silicon in NASICON'S framework are understood, and the change in chemical shifts of ³¹P and ²⁹Si caused by the substitution of lattice positions of atoms are explained. This is the first NMR investigation on the compounds of Na_1-xZr_2-xNb_x(PO₄)₃ system.

Key words: Hydrotbennal synthesis, Ionic conductor, NMR

Yue Yong, Li Liyun, Zhou Fengqi, Pang Wenqin. NMR INVESTIGATION OF THE STRUCTURE OF NASICON TYPE COMPOUNDS[J]. Chinese Journal of Magnetic Resonance, 1992, 9(1): 75-80.

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NMR INVESTIGATION OF THE STRUCTURE OF NASICON TYPE COMPOUNDS

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