THE STUDY OF 1H NMR ON THE PROTONS IN SOLUTION CONTAINING Cr(Ⅲ)

Chinese Journal of Magnetic Resonance ›› 1993, Vol. 10 ›› Issue (3): 303-308.

Previous Articles Next Articles

THE STUDY OF ¹H NMR ON THE PROTONS IN SOLUTION CONTAINING Cr(Ⅲ)

Shan Zhihua, Liu Qizhe, Zu Zhenhe, He Youjie

Chengdu University of Sci. & Tech., Chengdu 610065

Received:1992-03-02 Revised:1992-11-03 Published:1993-09-05 Online:2018-01-20

Abstract

Abstract: A study of the exchange process between the protons in a hydrated Cr(Ⅲ) ion and bulk was made with ¹H NMR. In the region of pH=0-3.17, the average lifetime of the protons in hydration sphere is of 10s order. There is a dynamic exchange process of protons with a mixture of first and second-order in pH=0-0.76 and only first order in pH=0.76-1.6. In system of Cr(Ⅲ)-H₂O-Gly, it was found that the protons in hydration sphere have activity weaken.

Key words: Hydrated Cr (Ⅲ) ion, Exchange rate, Average lifetime, Reaction dynamics, NMR

Shan Zhihua, Liu Qizhe, Zu Zhenhe, He Youjie. THE STUDY OF ¹H NMR ON THE PROTONS IN SOLUTION CONTAINING Cr(Ⅲ)[J]. Chinese Journal of Magnetic Resonance, 1993, 10(3): 303-308.

[1]	KOU Xinhui, ZHANG Yubing. Study on the Enantiomeric Recognition of Chiral Ureas Containing Amino Acid Units [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 221-230.
[2]	DU Qunjie. Experimental Study on Accurate Determination of Shale Porosity by Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 275-284.
[3]	JIANG Chaochao, YAO Shouquan, XU Juncheng, JIANG Yu. Design of the Broadband Magnetic Resonance Microcoil [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 299-307.
[4]	LI Keyan, CHENG Xin, CHEN Junfei, CAO Li, HUANG Zhen, LIU Chaoyang. Development of Low-noise Preamplifier for Low-field NMR [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 321-333.
[5]	LI Yujiang, ZHAO Wei, TAO Le, LU Bohua, ZHENG Guo, ZHANG Haiyan, GUO Xiaohe, ZHAO Tianzeng. NMR Data Analysis of Acarbose [J]. Chinese Journal of Magnetic Resonance, 2025, 42(2): 184-194.
[6]	ZHANG Jiayu, NIE Wenbo, TU Zhao, ZHENG Limin, WANG Yan, YANG Chunsheng. Three-Dimensional Structures of 3/4/5-O-feruloylquinic Acids by NMR Spectroscopy and Quantum Chemistry Calculation [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 47-55.
[7]	SHEN Xueyuan, WANG Ruichen, QI Guodong, XU Jun, DENG Feng. Design of in situ Solid-State NMR Rotor Inserts and Their Application to Catalytic Reactions [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 13-21.
[8]	SHEN Zhiqiang, DENG Yabo, YANG Peiju, HU Xiaoxue, HUANG Xiaojuan, XU Chuanzhi, SONG Huanling. Design and Application of an in situ NMR Device for Light-Induced Reaction Systems [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 22-33.
[9]	LIU Hongbing, LIU Huili, LUO Liting, SUN Lijuan, CHEN Lei. Identification and Structural Characterization of an Unknown Trace Degradation Impurity in Cabazitaxel Injection by LC-DAD-SPE-NMR/MS [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 34-46.
[10]	LI Mingdao, YAO Shouquan, XU Juncheng, LV Xinglong, HE Fengcheng, JIANG Yu. Design of the Handheld NMR Console [J]. Chinese Journal of Magnetic Resonance, 2024, 41(3): 257-265.
[11]	WANG Xingle, SHAO Zhengze, DONG Hongchun, WEI Daxiu, CHEN Qun, YAO Yefeng. Studies on the ¹H NMR Spectral Features of Hydrogen Molecules in the Interstices of SiO₂ Particles [J]. Chinese Journal of Magnetic Resonance, 2024, 41(3): 315-321.
[12]	YANG Yu, CHEN Bo, WU Liubin, LIN Enping, HUANG Yuqing, CHEN Zhong. Spectrum Reconstruction for Laplace NMR: From Handcraft Regularization to Deep Learning [J]. Chinese Journal of Magnetic Resonance, 2024, 41(2): 191-208.
[13]	MA Yingying, ZHANG Gong, LIAO Zhongshu. A Method for Improving the Measurement Accuracy of Nuclear Magnetic Resonance Fast Relaxation Signal [J]. Chinese Journal of Magnetic Resonance, 2024, 41(2): 162-172.
[14]	ZHU Xiaofeng, ZHAO Zhihong, TAN Rui, ZHOU Long, WANG Yichuan, LIU Wenjing, ZHANG Minghui, LIU Huabing. Water Migration Characteristics of Pinus Sylvestris During the Drying Process Studied by Single-sided Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2024, 41(2): 173-183.
[15]	WANG Ziwen, XIN Jiaxiang, WEI Daxiu, YAO Yefeng. Preparation Efficiency of Singlet States in Multi-spin Systems with Different Coupling Configurations [J]. Chinese Journal of Magnetic Resonance, 2024, 41(1): 67-76.

THE STUDY OF ¹H NMR ON THE PROTONS IN SOLUTION CONTAINING Cr(Ⅲ)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments