Chinese Journal of Magnetic Resonance ›› 1990, Vol. 7 ›› Issue (2): 153-159.

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13C-NMR STUDY ON CARBONYLATION OF TOLUENE (Ⅱ)

Wu Daxu, Zheng Yu, Chen Zhengming   

  1. Fujian Institute of Research on the Structure of Matter Acadetrda Sinica Fuzhou
  • Received:1989-01-11 Revised:1989-06-12 Published:1990-06-05 Online:2018-01-23

Abstract: The tracer experiments of the passing CO-HCl mixture through Toluene-Aluminum Chloride-Hydrogen Chloride system were described by 13C-NMR.The results suggest that the intermidiate complex of thecarbonylation of Toluene is  AlCl4-, the reaction mechanism is also discussed.

Key words: Toluene, Carbonylation, NMR