Quantitative Analysis of Cantharidin by 1H NMR and UV

Abstract

Abstract:

The ¹H NMR spectrum and UV spectrum of cantharidin isolated from the body fluid of Epicauta aptera Kaszab were obtained. Discrepancies were found between our spectral results and those reported in published references. The mechanisms that had potentially led to such discrepancies were discussed.

Key words: NMR, cantharidin, UV

CLC Number:

O482.53

Cite this article

FENG Qin-Zhong, ZHOU Jian-Wei. Quantitative Analysis of Cantharidin by ¹H NMR and UV[J]. Chinese Journal of Magnetic Resonance, 2010, 27(1): 121-125.

share this article

0
/ / Recommend

Add to citation manager EndNote|Reference Manager|ProCite|BibTeX|RefWorks

URL: http://magres.apm.ac.cn/EN/

http://magres.apm.ac.cn/EN/Y2010/V27/I1/121

References

[1] Fang Yu-ling(方宇凌), Tan Juan-ji（谭娟杰）, Ma Wen-zhen（马文珍），et al. The natural resource and content of cantharidin in the adult of meloids in China(芫菁科不同种类成虫体内斑蝥素的含量)[J]. Acta Entomologica Sinica(昆虫学报), 2001, 44(2): 192-196.

[2] Zou Jian-jun(邹建军)，Jiang Chun-lian(蒋春莲)，Zhang Sheng-qiang(张胜强)，et al. Quantitative determination of cantharidin lipid emulsion by HPLC(RP-HPLC法测定斑蝥素脂肪乳剂中斑蝥素的含量)[J]. Pharmaceutical and Clinical Research(江苏药学与临床研究), 2003，11（5）：31-33.

[3] Gadamer J. The constitution of cantharidin[J]. Arch Pharm, 1914, 252: 609-632.

[4] Huang Tian-shou（黄天守）. Encyclopedia of chemicals & drugs(化学化工药学大辞典)[Ｍ]. Taibei, China(台北）: The University Book Publishing Company（大学图书公司), 1982. 117.

Related Articles 15

[1]	KOU Xinhui, ZHANG Yubing. Study on the Enantiomeric Recognition of Chiral Ureas Containing Amino Acid Units [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 221-230.
[2]	DU Qunjie. Experimental Study on Accurate Determination of Shale Porosity by Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 275-284.
[3]	JIANG Chaochao, YAO Shouquan, XU Juncheng, JIANG Yu. Design of the Broadband Magnetic Resonance Microcoil [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 299-307.
[4]	LI Keyan, CHENG Xin, CHEN Junfei, CAO Li, HUANG Zhen, LIU Chaoyang. Development of Low-noise Preamplifier for Low-field NMR [J]. Chinese Journal of Magnetic Resonance, 2025, 42(3): 321-333.
[5]	LI Yujiang, ZHAO Wei, TAO Le, LU Bohua, ZHENG Guo, ZHANG Haiyan, GUO Xiaohe, ZHAO Tianzeng. NMR Data Analysis of Acarbose [J]. Chinese Journal of Magnetic Resonance, 2025, 42(2): 184-194.
[6]	ZHANG Jiayu, NIE Wenbo, TU Zhao, ZHENG Limin, WANG Yan, YANG Chunsheng. Three-Dimensional Structures of 3/4/5-O-feruloylquinic Acids by NMR Spectroscopy and Quantum Chemistry Calculation [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 47-55.
[7]	SHEN Xueyuan, WANG Ruichen, QI Guodong, XU Jun, DENG Feng. Design of in situ Solid-State NMR Rotor Inserts and Their Application to Catalytic Reactions [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 13-21.
[8]	SHEN Zhiqiang, DENG Yabo, YANG Peiju, HU Xiaoxue, HUANG Xiaojuan, XU Chuanzhi, SONG Huanling. Design and Application of an in situ NMR Device for Light-Induced Reaction Systems [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 22-33.
[9]	LIU Hongbing, LIU Huili, LUO Liting, SUN Lijuan, CHEN Lei. Identification and Structural Characterization of an Unknown Trace Degradation Impurity in Cabazitaxel Injection by LC-DAD-SPE-NMR/MS [J]. Chinese Journal of Magnetic Resonance, 2025, 42(1): 34-46.
[10]	LI Mingdao, YAO Shouquan, XU Juncheng, LV Xinglong, HE Fengcheng, JIANG Yu. Design of the Handheld NMR Console [J]. Chinese Journal of Magnetic Resonance, 2024, 41(3): 257-265.
[11]	WANG Xingle, SHAO Zhengze, DONG Hongchun, WEI Daxiu, CHEN Qun, YAO Yefeng. Studies on the ¹H NMR Spectral Features of Hydrogen Molecules in the Interstices of SiO₂ Particles [J]. Chinese Journal of Magnetic Resonance, 2024, 41(3): 315-321.
[12]	YANG Yu, CHEN Bo, WU Liubin, LIN Enping, HUANG Yuqing, CHEN Zhong. Spectrum Reconstruction for Laplace NMR: From Handcraft Regularization to Deep Learning [J]. Chinese Journal of Magnetic Resonance, 2024, 41(2): 191-208.
[13]	MA Yingying, ZHANG Gong, LIAO Zhongshu. A Method for Improving the Measurement Accuracy of Nuclear Magnetic Resonance Fast Relaxation Signal [J]. Chinese Journal of Magnetic Resonance, 2024, 41(2): 162-172.
[14]	ZHU Xiaofeng, ZHAO Zhihong, TAN Rui, ZHOU Long, WANG Yichuan, LIU Wenjing, ZHANG Minghui, LIU Huabing. Water Migration Characteristics of Pinus Sylvestris During the Drying Process Studied by Single-sided Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2024, 41(2): 173-183.
[15]	WANG Ziwen, XIN Jiaxiang, WEI Daxiu, YAO Yefeng. Preparation Efficiency of Singlet States in Multi-spin Systems with Different Coupling Configurations [J]. Chinese Journal of Magnetic Resonance, 2024, 41(1): 67-76.

Metrics

Viewed

Full text

Abstract

Comments

Abstract
References
Related Articles
Recommended Articles
Metrics
Comments

TOP

Quantitative Analysis of Cantharidin by ¹H NMR and UV

PDF (PC)

Knowledge