TRANSITION-METAL COMPOUNDS WITH BIDENTATE LIGANDS Ⅱ.NMR STUDY ON NICKEL-THIOTATES

Chinese Journal of Magnetic Resonance ›› 1990, Vol. 7 ›› Issue (2): 231-236.

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TRANSITION-METAL COMPOUNDS WITH BIDENTATE LIGANDS Ⅱ.NMR STUDY ON NICKEL-THIOTATES

Liu Hanqin, Wu Daxu, Chen Xuetai, Kang Beisheng

Fuzkou Laboratory of Structural Chemistry, Fuzhou, Fujian, 350002 and Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan, 430071

Received:1989-06-07 Revised:1989-08-24 Published:1990-06-05 Online:2018-01-23

Abstract

Abstract: ¹H NMR data of compounds I and Ⅱ reveal that both compounds are diamagnetic and stable in dimethylsulfoxide solution as their molecular structures remain the same as those in the solid state. NMR parameters are estimated by comparing the simulated spectra with the observed ones. Diamagnetic properties are confirmed by ¹³C NMR measurement.

Key words: Di-nuclear or tri-nuclear nickel compound, NMR, o-mercaptopbenol, Nickel thiolates, 1,2-propanedithiol

Liu Hanqin, Wu Daxu, Chen Xuetai, Kang Beisheng. TRANSITION-METAL COMPOUNDS WITH BIDENTATE LIGANDS Ⅱ.NMR STUDY ON NICKEL-THIOTATES[J]. Chinese Journal of Magnetic Resonance, 1990, 7(2): 231-236.

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TRANSITION-METAL COMPOUNDS WITH BIDENTATE LIGANDS Ⅱ.NMR STUDY ON NICKEL-THIOTATES

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